Fig. 7

delta[IrCl6]2– aq (M)	D Ir(IV)	(yEr+-)	
4.14197E-6		49.31493	2.46575
2.01658E-5		47.13491	2.35675
3.96352E-5		40.54645	2.02732
7.91067E-5		38.65198	1.9326
1.24455E-4		27.32702	1.36635
1.68267E-4		24.66883	1.23344
4.36269E-4		9.65994		0.483
6.93368E-4		8.32316		0.41616
7.76062E-4		5.16338		0.25817
0.00126			5.78636		0.28932				


Nonlinear curve fit was used to fit the data based on the equations in the paper:

delta[IrCl6]2– 	D Ir(IV)
aq (M)
4.14197E-6	44.23584
4.16575E-6	44.23253
4.18967E-6	44.2292
4.21372E-6	44.22585
4.23791E-6	44.22248
4.26225E-6	44.21909
4.28672E-6	44.21568
4.31133E-6	44.21225
4.33608E-6	44.20881
4.36098E-6	44.20534
4.38602E-6	44.20186
4.4112E-6	44.19835
4.43652E-6	44.19483
4.462E-6	44.19128
4.48761E-6	44.18772
4.51338E-6	44.18413
4.53929E-6	44.18052
4.56535E-6	44.1769
4.59157E-6	44.17325
4.61793E-6	44.16959
4.64444E-6	44.1659
4.67111E-6	44.16219
4.69792E-6	44.15846
4.7249E-6	44.15471
4.75202E-6	44.15094
4.77931E-6	44.14714
4.80675E-6	44.14333
4.83435E-6	44.13949
4.8621E-6	44.13563
4.89002E-6	44.13175
4.91809E-6	44.12785
4.94633E-6	44.12393
4.97473E-6	44.11998
5.00329E-6	44.11601
5.03202E-6	44.11202
5.06091E-6	44.10801
5.08996E-6	44.10397
5.11919E-6	44.09991
5.14858E-6	44.09583
5.17814E-6	44.09173
5.20787E-6	44.0876
5.23777E-6	44.08345
5.26784E-6	44.07927
5.29809E-6	44.07508
5.3285E-6	44.07085
5.3591E-6	44.06661
5.38987E-6	44.06234
5.42081E-6	44.05805
5.45193E-6	44.05373
5.48324E-6	44.04938
5.51472E-6	44.04502
5.54638E-6	44.04063
5.57822E-6	44.03621
5.61025E-6	44.03177
5.64246E-6	44.0273
5.67486E-6	44.02281
5.70744E-6	44.01829
5.74021E-6	44.01375
5.77316E-6	44.00918
5.80631E-6	44.00459
5.83965E-6	43.99997
5.87317E-6	43.99533
5.90689E-6	43.99065
5.94081E-6	43.98596
5.97492E-6	43.98123
6.00922E-6	43.97648
6.04372E-6	43.9717
6.07842E-6	43.9669
6.11332E-6	43.96207
6.14842E-6	43.95721
6.18372E-6	43.95232
6.21922E-6	43.94741
6.25493E-6	43.94247
6.29084E-6	43.9375
6.32696E-6	43.9325
6.36329E-6	43.92747
6.39982E-6	43.92242
6.43656E-6	43.91734
6.47352E-6	43.91223
6.51069E-6	43.90709
6.54807E-6	43.90192
6.58566E-6	43.89672
6.62347E-6	43.8915
6.6615E-6	43.88624
6.69975E-6	43.88095
6.73821E-6	43.87564
6.7769E-6	43.87029
6.81581E-6	43.86492
6.85494E-6	43.85951
6.8943E-6	43.85408
6.93388E-6	43.84861
6.97369E-6	43.84312
7.01373E-6	43.83759
7.054E-6	43.83203
7.0945E-6	43.82644
7.13523E-6	43.82082
7.1762E-6	43.81517
7.2174E-6	43.80948
7.25884E-6	43.80376
7.30051E-6	43.79802
7.34243E-6	43.79224
7.38458E-6	43.78642
7.42698E-6	43.78058
7.46962E-6	43.7747
7.51251E-6	43.76879
7.55564E-6	43.76284
7.59902E-6	43.75686
7.64265E-6	43.75085
7.68653E-6	43.74481
7.73066E-6	43.73873
7.77505E-6	43.73262
7.81969E-6	43.72647
7.86458E-6	43.72029
7.90973E-6	43.71407
7.95515E-6	43.70782
8.00082E-6	43.70153
8.04676E-6	43.69521
8.09296E-6	43.68886
8.13942E-6	43.68247
8.18615E-6	43.67604
8.23315E-6	43.66957
8.28042E-6	43.66307
8.32796E-6	43.65654
8.37578E-6	43.64996
8.42387E-6	43.64336
8.47223E-6	43.63671
8.52087E-6	43.63003
8.5698E-6	43.6233
8.619E-6	43.61655
8.66848E-6	43.60975
8.71825E-6	43.60292
8.76831E-6	43.59604
8.81865E-6	43.58913
8.86928E-6	43.58218
8.9202E-6	43.5752
8.97142E-6	43.56817
9.02293E-6	43.5611
9.07473E-6	43.554
9.12683E-6	43.54685
9.17923E-6	43.53967
9.23194E-6	43.53244
9.28494E-6	43.52518
9.33825E-6	43.51787
9.39186E-6	43.51053
9.44579E-6	43.50314
9.50002E-6	43.49571
9.55456E-6	43.48824
9.60942E-6	43.48073
9.66459E-6	43.47318
9.72008E-6	43.46558
9.77588E-6	43.45794
9.83201E-6	43.45026
9.88846E-6	43.44254
9.94523E-6	43.43477
1.00023E-5	43.42697
1.00598E-5	43.41911
1.01175E-5	43.41122
1.01756E-5	43.40328
1.0234E-5	43.39529
1.02928E-5	43.38727
1.03519E-5	43.37919
1.04113E-5	43.37108
1.04711E-5	43.36291
1.05312E-5	43.35471
1.05917E-5	43.34645
1.06525E-5	43.33815
1.07136E-5	43.32981
1.07752E-5	43.32142
1.0837E-5	43.31298
1.08992E-5	43.30449
1.09618E-5	43.29596
1.10248E-5	43.28738
1.10881E-5	43.27876
1.11517E-5	43.27008
1.12157E-5	43.26136
1.12801E-5	43.25259
1.13449E-5	43.24377
1.141E-5	43.2349
1.14755E-5	43.22598
1.15414E-5	43.21702
1.16077E-5	43.208
1.16743E-5	43.19894
1.17414E-5	43.18982
1.18088E-5	43.18065
1.18766E-5	43.17144
1.19448E-5	43.16217
1.20133E-5	43.15285
1.20823E-5	43.14348
1.21517E-5	43.13406
1.22215E-5	43.12458
1.22916E-5	43.11506
1.23622E-5	43.10548
1.24332E-5	43.09584
1.25046E-5	43.08616
1.25763E-5	43.07642
1.26486E-5	43.06663
1.27212E-5	43.05678
1.27942E-5	43.04688
1.28677E-5	43.03693
1.29415E-5	43.02692
1.30158E-5	43.01685
1.30906E-5	43.00673
1.31657E-5	42.99656
1.32413E-5	42.98633
1.33173E-5	42.97604
1.33938E-5	42.96569
1.34707E-5	42.95529
1.3548E-5	42.94483
1.36258E-5	42.93432
1.37041E-5	42.92374
1.37827E-5	42.91311
1.38619E-5	42.90242
1.39415E-5	42.89167
1.40215E-5	42.88087
1.4102E-5	42.87
1.4183E-5	42.85907
1.42644E-5	42.84809
1.43463E-5	42.83704
1.44287E-5	42.82593
1.45115E-5	42.81476
1.45948E-5	42.80354
1.46786E-5	42.79224
1.47629E-5	42.78089
1.48477E-5	42.76948
1.49329E-5	42.758
1.50186E-5	42.74646
1.51049E-5	42.73486
1.51916E-5	42.72319
1.52788E-5	42.71146
1.53665E-5	42.69967
1.54548E-5	42.68781
1.55435E-5	42.67589
1.56327E-5	42.6639
1.57225E-5	42.65185
1.58128E-5	42.63973
1.59035E-5	42.62754
1.59949E-5	42.61529
1.60867E-5	42.60297
1.6179E-5	42.59059
1.62719E-5	42.57813
1.63654E-5	42.56561
1.64593E-5	42.55302
1.65538E-5	42.54037
1.66489E-5	42.52764
1.67445E-5	42.51485
1.68406E-5	42.50198
1.69373E-5	42.48905
1.70345E-5	42.47604
1.71323E-5	42.46297
1.72307E-5	42.44982
1.73296E-5	42.4366
1.74291E-5	42.42331
1.75292E-5	42.40995
1.76298E-5	42.39652
1.7731E-5	42.38301
1.78328E-5	42.36943
1.79352E-5	42.35578
1.80382E-5	42.34205
1.81418E-5	42.32825
1.82459E-5	42.31437
1.83507E-5	42.30042
1.8456E-5	42.2864
1.8562E-5	42.2723
1.86686E-5	42.25812
1.87758E-5	42.24386
1.88836E-5	42.22953
1.8992E-5	42.21512
1.9101E-5	42.20063
1.92107E-5	42.18607
1.9321E-5	42.17143
1.94319E-5	42.1567
1.95435E-5	42.1419
1.96557E-5	42.12702
1.97685E-5	42.11206
1.9882E-5	42.09702
1.99962E-5	42.0819
2.0111E-5	42.06669
2.02265E-5	42.05141
2.03426E-5	42.03604
2.04594E-5	42.02059
2.05768E-5	42.00506
2.0695E-5	41.98944
2.08138E-5	41.97374
2.09333E-5	41.95796
2.10535E-5	41.94209
2.11744E-5	41.92614
2.12959E-5	41.9101
2.14182E-5	41.89398
2.15412E-5	41.87777
2.16648E-5	41.86147
2.17892E-5	41.84509
2.19143E-5	41.82861
2.20402E-5	41.81205
2.21667E-5	41.79541
2.2294E-5	41.77867
2.2422E-5	41.76184
2.25507E-5	41.74493
2.26802E-5	41.72792
2.28104E-5	41.71083
2.29413E-5	41.69364
2.30731E-5	41.67636
2.32055E-5	41.65899
2.33388E-5	41.64153
2.34728E-5	41.62397
2.36075E-5	41.60632
2.37431E-5	41.58858
2.38794E-5	41.57075
2.40165E-5	41.55282
2.41544E-5	41.53479
2.42931E-5	41.51667
2.44325E-5	41.49845
2.45728E-5	41.48014
2.47139E-5	41.46173
2.48558E-5	41.44322
2.49985E-5	41.42462
2.5142E-5	41.40591
2.52864E-5	41.38711
2.54316E-5	41.36821
2.55776E-5	41.34921
2.57244E-5	41.33011
2.58721E-5	41.31091
2.60207E-5	41.2916
2.617E-5	41.2722
2.63203E-5	41.25269
2.64714E-5	41.23309
2.66234E-5	41.21337
2.67763E-5	41.19356
2.693E-5	41.17364
2.70846E-5	41.15362
2.72401E-5	41.13349
2.73965E-5	41.11325
2.75538E-5	41.09292
2.7712E-5	41.07247
2.78711E-5	41.05192
2.80311E-5	41.03126
2.81921E-5	41.01049
2.83539E-5	40.98961
2.85167E-5	40.96863
2.86804E-5	40.94753
2.88451E-5	40.92633
2.90107E-5	40.90501
2.91773E-5	40.88359
2.93448E-5	40.86205
2.95133E-5	40.8404
2.96827E-5	40.81864
2.98531E-5	40.79676
3.00245E-5	40.77478
3.01969E-5	40.75267
3.03703E-5	40.73046
3.05447E-5	40.70812
3.072E-5	40.68568
3.08964E-5	40.66311
3.10738E-5	40.64043
3.12522E-5	40.61764
3.14316E-5	40.59472
3.16121E-5	40.57169
3.17936E-5	40.54854
3.19761E-5	40.52527
3.21597E-5	40.50188
3.23444E-5	40.47837
3.25301E-5	40.45474
3.27168E-5	40.43098
3.29047E-5	40.40711
3.30936E-5	40.38311
3.32836E-5	40.35899
3.34747E-5	40.33475
3.36669E-5	40.31038
3.38602E-5	40.28588
3.40546E-5	40.26127
3.42501E-5	40.23652
3.44467E-5	40.21165
3.46445E-5	40.18666
3.48434E-5	40.16153
3.50435E-5	40.13628
3.52447E-5	40.1109
3.5447E-5	40.08539
3.56505E-5	40.05975
3.58552E-5	40.03398
3.60611E-5	40.00808
3.62681E-5	39.98205
3.64764E-5	39.95589
3.66858E-5	39.92959
3.68964E-5	39.90316
3.71083E-5	39.8766
3.73213E-5	39.8499
3.75356E-5	39.82307
3.77511E-5	39.79611
3.79678E-5	39.769
3.81858E-5	39.74177
3.84051E-5	39.71439
3.86256E-5	39.68688
3.88473E-5	39.65923
3.90704E-5	39.63144
3.92947E-5	39.60351
3.95203E-5	39.57544
3.97472E-5	39.54723
3.99754E-5	39.51888
4.02049E-5	39.49039
4.04357E-5	39.46175
4.06679E-5	39.43298
4.09014E-5	39.40406
4.11362E-5	39.37499
4.13724E-5	39.34578
4.16099E-5	39.31643
4.18488E-5	39.28693
4.20891E-5	39.25728
4.23308E-5	39.22749
4.25738E-5	39.19755
4.28182E-5	39.16746
4.30641E-5	39.13723
4.33113E-5	39.10684
4.356E-5	39.0763
4.38101E-5	39.04562
4.40616E-5	39.01478
4.43146E-5	38.98379
4.4569E-5	38.95265
4.48249E-5	38.92136
4.50823E-5	38.88991
4.53411E-5	38.85831
4.56014E-5	38.82655
4.58632E-5	38.79464
4.61266E-5	38.76258
4.63914E-5	38.73035
4.66577E-5	38.69797
4.69256E-5	38.66544
4.7195E-5	38.63274
4.7466E-5	38.59989
4.77385E-5	38.56687
4.80126E-5	38.5337
4.82883E-5	38.50037
4.85655E-5	38.46687
4.88443E-5	38.43321
4.91248E-5	38.3994
4.94068E-5	38.36541
4.96905E-5	38.33127
4.99758E-5	38.29696
5.02627E-5	38.26248
5.05513E-5	38.22784
5.08415E-5	38.19304
5.11334E-5	38.15806
5.1427E-5	38.12292
5.17223E-5	38.08762
5.20192E-5	38.05214
5.23179E-5	38.0165
5.26183E-5	37.98068
5.29204E-5	37.9447
5.32242E-5	37.90854
5.35298E-5	37.87222
5.38371E-5	37.83572
5.41462E-5	37.79905
5.44571E-5	37.7622
5.47698E-5	37.72519
5.50842E-5	37.688
5.54005E-5	37.65063
5.57186E-5	37.61309
5.60385E-5	37.57537
5.63602E-5	37.53747
5.66838E-5	37.4994
5.70092E-5	37.46115
5.73365E-5	37.42272
5.76657E-5	37.38411
5.79968E-5	37.34533
5.83298E-5	37.30636
5.86647E-5	37.26721
5.90015E-5	37.22788
5.93403E-5	37.18837
5.9681E-5	37.14868
6.00236E-5	37.1088
6.03682E-5	37.06874
6.07148E-5	37.0285
6.10634E-5	36.98807
6.1414E-5	36.94745
6.17666E-5	36.90665
6.21212E-5	36.86566
6.24779E-5	36.82449
6.28366E-5	36.78313
6.31974E-5	36.74158
6.35602E-5	36.69984
6.39251E-5	36.65791
6.42922E-5	36.61579
6.46613E-5	36.57348
6.50325E-5	36.53098
6.54059E-5	36.48829
6.57814E-5	36.44541
6.61591E-5	36.40233
6.6539E-5	36.35906
6.6921E-5	36.3156
6.73052E-5	36.27194
6.76916E-5	36.22809
6.80803E-5	36.18404
6.84712E-5	36.13979
6.88643E-5	36.09535
6.92596E-5	36.05072
6.96573E-5	36.00588
7.00572E-5	35.96085
7.04595E-5	35.91562
7.0864E-5	35.87019
7.12708E-5	35.82456
7.168E-5	35.77873
7.20916E-5	35.7327
7.25055E-5	35.68647
7.29218E-5	35.64003
7.33404E-5	35.5934
7.37615E-5	35.54656
7.4185E-5	35.49952
7.46109E-5	35.45228
7.50393E-5	35.40483
7.54701E-5	35.35718
7.59035E-5	35.30932
7.63392E-5	35.26125
7.67775E-5	35.21299
7.72184E-5	35.16451
7.76617E-5	35.11583
7.81076E-5	35.06694
7.8556E-5	35.01784
7.9007E-5	34.96854
7.94607E-5	34.91902
7.99169E-5	34.8693
8.03757E-5	34.81937
8.08372E-5	34.76922
8.13013E-5	34.71887
8.17681E-5	34.66831
8.22375E-5	34.61753
8.27097E-5	34.56655
8.31846E-5	34.51535
8.36622E-5	34.46394
8.41425E-5	34.41231
8.46256E-5	34.36048
8.51115E-5	34.30843
8.56001E-5	34.25616
8.60916E-5	34.20368
8.65859E-5	34.15099
8.7083E-5	34.09808
8.7583E-5	34.04496
8.80858E-5	33.99162
8.85916E-5	33.93807
8.91002E-5	33.8843
8.96118E-5	33.83031
9.01263E-5	33.7761
9.06437E-5	33.72168
9.11641E-5	33.66704
9.16875E-5	33.61218
9.2214E-5	33.55711
9.27434E-5	33.50181
9.32759E-5	33.4463
9.38114E-5	33.39057
9.435E-5	33.33462
9.48917E-5	33.27844
9.54365E-5	33.22205
9.59845E-5	33.16544
9.65356E-5	33.10861
9.70898E-5	33.05156
9.76472E-5	32.99429
9.82079E-5	32.93679
9.87717E-5	32.87908
9.93388E-5	32.82114
9.99092E-5	32.76299
1.00483E-4	32.70461
1.0106E-4	32.646
1.0164E-4	32.58718
1.02223E-4	32.52814
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