Hydrophobic polymerized ionic liquids for trace metal solid phase extraction: thallium transfer from hydrochloric acid media DOI: 10.1039/C9NJ00689C Time, min [TlCl4-]aq^(-3), M^(-3) +/- Time, min_line [TlCl4-]aq^(-3), M^(-3)_line 0 1.26E+15 7.56E+13 0 0 5 3.48E+17 2.09E+16 0.06006 4.45E+15 15 1.11E+18 6.68E+16 0.12012 8.91E+15 30 2.23E+18 1.34E+17 0.18018 1.34E+16 60 2.59E+18 1.56E+17 0.24024 1.78E+16 0.3003 2.23E+16 0.36036 2.67E+16 0.42042 3.12E+16 0.48048 3.56E+16 0.54054 4.01E+16 0.6006 4.45E+16 0.66066 4.90E+16 0.72072 5.34E+16 0.78078 5.79E+16 0.84084 6.23E+16 0.9009 6.68E+16 0.96096 7.12E+16 1.02102 7.57E+16 1.08108 8.02E+16 1.14114 8.46E+16 1.2012 8.91E+16 1.26126 9.35E+16 1.32132 9.80E+16 1.38138 1.02E+17 1.44144 1.07E+17 1.5015 1.11E+17 1.56156 1.16E+17 1.62162 1.20E+17 1.68168 1.25E+17 1.74174 1.29E+17 1.8018 1.34E+17 1.86186 1.38E+17 1.92192 1.42E+17 1.98198 1.47E+17 2.04204 1.51E+17 2.1021 1.56E+17 2.16216 1.60E+17 2.22222 1.65E+17 2.28228 1.69E+17 2.34234 1.74E+17 2.4024 1.78E+17 2.46246 1.83E+17 2.52252 1.87E+17 2.58258 1.91E+17 2.64264 1.96E+17 2.7027 2.00E+17 2.76276 2.05E+17 2.82282 2.09E+17 2.88288 2.14E+17 2.94294 2.18E+17 3.003 2.23E+17 3.06306 2.27E+17 3.12312 2.32E+17 3.18318 2.36E+17 3.24324 2.40E+17 3.3033 2.45E+17 3.36336 2.49E+17 3.42342 2.54E+17 3.48348 2.58E+17 3.54354 2.63E+17 3.6036 2.67E+17 3.66366 2.72E+17 3.72372 2.76E+17 3.78378 2.81E+17 3.84384 2.85E+17 3.9039 2.89E+17 3.96396 2.94E+17 4.02402 2.98E+17 4.08408 3.03E+17 4.14414 3.07E+17 4.2042 3.12E+17 4.26426 3.16E+17 4.32432 3.21E+17 4.38438 3.25E+17 4.44444 3.30E+17 4.5045 3.34E+17 4.56456 3.38E+17 4.62462 3.43E+17 4.68468 3.47E+17 4.74474 3.52E+17 4.8048 3.56E+17 4.86486 3.61E+17 4.92492 3.65E+17 4.98498 3.70E+17 5.04505 3.74E+17 5.10511 3.78E+17 5.16517 3.83E+17 5.22523 3.87E+17 5.28529 3.92E+17 5.34535 3.96E+17 5.40541 4.01E+17 5.46547 4.05E+17 5.52553 4.10E+17 5.58559 4.14E+17 5.64565 4.19E+17 5.70571 4.23E+17 5.76577 4.27E+17 5.82583 4.32E+17 5.88589 4.36E+17 5.94595 4.41E+17 6.00601 4.45E+17 6.06607 4.50E+17 6.12613 4.54E+17 6.18619 4.59E+17 6.24625 4.63E+17 6.30631 4.68E+17 6.36637 4.72E+17 6.42643 4.76E+17 6.48649 4.81E+17 6.54655 4.85E+17 6.60661 4.90E+17 6.66667 4.94E+17 6.72673 4.99E+17 6.78679 5.03E+17 6.84685 5.08E+17 6.90691 5.12E+17 6.96697 5.17E+17 7.02703 5.21E+17 7.08709 5.25E+17 7.14715 5.30E+17 7.20721 5.34E+17 7.26727 5.39E+17 7.32733 5.43E+17 7.38739 5.48E+17 7.44745 5.52E+17 7.50751 5.57E+17 7.56757 5.61E+17 7.62763 5.66E+17 7.68769 5.70E+17 7.74775 5.74E+17 7.80781 5.79E+17 7.86787 5.83E+17 7.92793 5.88E+17 7.98799 5.92E+17 8.04805 5.97E+17 8.10811 6.01E+17 8.16817 6.06E+17 8.22823 6.10E+17 8.28829 6.15E+17 8.34835 6.19E+17 8.40841 6.23E+17 8.46847 6.28E+17 8.52853 6.32E+17 8.58859 6.37E+17 8.64865 6.41E+17 8.70871 6.46E+17 8.76877 6.50E+17 8.82883 6.55E+17 8.88889 6.59E+17 8.94895 6.63E+17 9.00901 6.68E+17 9.06907 6.72E+17 9.12913 6.77E+17 9.18919 6.81E+17 9.24925 6.86E+17 9.30931 6.90E+17 9.36937 6.95E+17 9.42943 6.99E+17 9.48949 7.04E+17 9.54955 7.08E+17 9.60961 7.12E+17 9.66967 7.17E+17 9.72973 7.21E+17 9.78979 7.26E+17 9.84985 7.30E+17 9.90991 7.35E+17 9.96997 7.39E+17 10.03003 7.44E+17 10.09009 7.48E+17 10.15015 7.53E+17 10.21021 7.57E+17 10.27027 7.61E+17 10.33033 7.66E+17 10.39039 7.70E+17 10.45045 7.75E+17 10.51051 7.79E+17 10.57057 7.84E+17 10.63063 7.88E+17 10.69069 7.93E+17 10.75075 7.97E+17 10.81081 8.02E+17 10.87087 8.06E+17 10.93093 8.10E+17 10.99099 8.15E+17 11.05105 8.19E+17 11.11111 8.24E+17 11.17117 8.28E+17 11.23123 8.33E+17 11.29129 8.37E+17 11.35135 8.42E+17 11.41141 8.46E+17 11.47147 8.51E+17 11.53153 8.55E+17 11.59159 8.59E+17 11.65165 8.64E+17 11.71171 8.68E+17 11.77177 8.73E+17 11.83183 8.77E+17 11.89189 8.82E+17 11.95195 8.86E+17 12.01201 8.91E+17 12.07207 8.95E+17 12.13213 8.99E+17 12.19219 9.04E+17 12.25225 9.08E+17 12.31231 9.13E+17 12.37237 9.17E+17 12.43243 9.22E+17 12.49249 9.26E+17 12.55255 9.31E+17 12.61261 9.35E+17 12.67267 9.40E+17 12.73273 9.44E+17 12.79279 9.48E+17 12.85285 9.53E+17 12.91291 9.57E+17 12.97297 9.62E+17 13.03303 9.66E+17 13.09309 9.71E+17 13.15315 9.75E+17 13.21321 9.80E+17 13.27327 9.84E+17 13.33333 9.89E+17 13.39339 9.93E+17 13.45345 9.97E+17 13.51351 1.00E+18 13.57357 1.01E+18 13.63363 1.01E+18 13.69369 1.02E+18 13.75375 1.02E+18 13.81381 1.02E+18 13.87387 1.03E+18 13.93393 1.03E+18 13.99399 1.04E+18 14.05405 1.04E+18 14.11411 1.05E+18 14.17417 1.05E+18 14.23423 1.06E+18 14.29429 1.06E+18 14.35435 1.06E+18 14.41441 1.07E+18 14.47447 1.07E+18 14.53453 1.08E+18 14.59459 1.08E+18 14.65465 1.09E+18 14.71471 1.09E+18 14.77477 1.10E+18 14.83483 1.10E+18 14.89489 1.10E+18 14.95495 1.11E+18 15.01502 1.11E+18 15.07508 1.12E+18 15.13514 1.12E+18 15.1952 1.13E+18 15.25526 1.13E+18 15.31532 1.14E+18 15.37538 1.14E+18 15.43544 1.14E+18 15.4955 1.15E+18 15.55556 1.15E+18 15.61562 1.16E+18 15.67568 1.16E+18 15.73574 1.17E+18 15.7958 1.17E+18 15.85586 1.18E+18 15.91592 1.18E+18 15.97598 1.18E+18 16.03604 1.19E+18 16.0961 1.19E+18 16.15616 1.20E+18 16.21622 1.20E+18 16.27628 1.21E+18 16.33634 1.21E+18 16.3964 1.22E+18 16.45646 1.22E+18 16.51652 1.22E+18 16.57658 1.23E+18 16.63664 1.23E+18 16.6967 1.24E+18 16.75676 1.24E+18 16.81682 1.25E+18 16.87688 1.25E+18 16.93694 1.26E+18 16.997 1.26E+18 17.05706 1.26E+18 17.11712 1.27E+18 17.17718 1.27E+18 17.23724 1.28E+18 17.2973 1.28E+18 17.35736 1.29E+18 17.41742 1.29E+18 17.47748 1.30E+18 17.53754 1.30E+18 17.5976 1.30E+18 17.65766 1.31E+18 17.71772 1.31E+18 17.77778 1.32E+18 17.83784 1.32E+18 17.8979 1.33E+18 17.95796 1.33E+18 18.01802 1.34E+18 18.07808 1.34E+18 18.13814 1.34E+18 18.1982 1.35E+18 18.25826 1.35E+18 18.31832 1.36E+18 18.37838 1.36E+18 18.43844 1.37E+18 18.4985 1.37E+18 18.55856 1.38E+18 18.61862 1.38E+18 18.67868 1.38E+18 18.73874 1.39E+18 18.7988 1.39E+18 18.85886 1.40E+18 18.91892 1.40E+18 18.97898 1.41E+18 19.03904 1.41E+18 19.0991 1.42E+18 19.15916 1.42E+18 19.21922 1.42E+18 19.27928 1.43E+18 19.33934 1.43E+18 19.3994 1.44E+18 19.45946 1.44E+18 19.51952 1.45E+18 19.57958 1.45E+18 19.63964 1.46E+18 19.6997 1.46E+18 19.75976 1.47E+18 19.81982 1.47E+18 19.87988 1.47E+18 19.93994 1.48E+18 20 1.48E+18 20.06006 1.49E+18 20.12012 1.49E+18 20.18018 1.50E+18 20.24024 1.50E+18 20.3003 1.51E+18 20.36036 1.51E+18 20.42042 1.51E+18 20.48048 1.52E+18 20.54054 1.52E+18 20.6006 1.53E+18 20.66066 1.53E+18 20.72072 1.54E+18 20.78078 1.54E+18 20.84084 1.55E+18 20.9009 1.55E+18 20.96096 1.55E+18 21.02102 1.56E+18 21.08108 1.56E+18 21.14114 1.57E+18 21.2012 1.57E+18 21.26126 1.58E+18 21.32132 1.58E+18 21.38138 1.59E+18 21.44144 1.59E+18 21.5015 1.59E+18 21.56156 1.60E+18 21.62162 1.60E+18 21.68168 1.61E+18 21.74174 1.61E+18 21.8018 1.62E+18 21.86186 1.62E+18 21.92192 1.63E+18 21.98198 1.63E+18 22.04204 1.63E+18 22.1021 1.64E+18 22.16216 1.64E+18 22.22222 1.65E+18 22.28228 1.65E+18 22.34234 1.66E+18 22.4024 1.66E+18 22.46246 1.67E+18 22.52252 1.67E+18 22.58258 1.67E+18 22.64264 1.68E+18 22.7027 1.68E+18 22.76276 1.69E+18 22.82282 1.69E+18 22.88288 1.70E+18 22.94294 1.70E+18 23.003 1.71E+18 23.06306 1.71E+18 23.12312 1.71E+18 23.18318 1.72E+18 23.24324 1.72E+18 23.3033 1.73E+18 23.36336 1.73E+18 23.42342 1.74E+18 23.48348 1.74E+18 23.54354 1.75E+18 23.6036 1.75E+18 23.66366 1.75E+18 23.72372 1.76E+18 23.78378 1.76E+18 23.84384 1.77E+18 23.9039 1.77E+18 23.96396 1.78E+18 24.02402 1.78E+18 24.08408 1.79E+18 24.14414 1.79E+18 24.2042 1.79E+18 24.26426 1.80E+18 24.32432 1.80E+18 24.38438 1.81E+18 24.44444 1.81E+18 24.5045 1.82E+18 24.56456 1.82E+18 24.62462 1.83E+18 24.68468 1.83E+18 24.74474 1.83E+18 24.8048 1.84E+18 24.86486 1.84E+18 24.92492 1.85E+18 24.98498 1.85E+18 25.04505 1.86E+18 25.10511 1.86E+18 25.16517 1.87E+18 25.22523 1.87E+18 25.28529 1.87E+18 25.34535 1.88E+18 25.40541 1.88E+18 25.46547 1.89E+18 25.52553 1.89E+18 25.58559 1.90E+18 25.64565 1.90E+18 25.70571 1.91E+18 25.76577 1.91E+18 25.82583 1.91E+18 25.88589 1.92E+18 25.94595 1.92E+18 26.00601 1.93E+18 26.06607 1.93E+18 26.12613 1.94E+18 26.18619 1.94E+18 26.24625 1.95E+18 26.30631 1.95E+18 26.36637 1.95E+18 26.42643 1.96E+18 26.48649 1.96E+18 26.54655 1.97E+18 26.60661 1.97E+18 26.66667 1.98E+18 26.72673 1.98E+18 26.78679 1.99E+18 26.84685 1.99E+18 26.90691 1.99E+18 26.96697 2.00E+18 27.02703 2.00E+18 27.08709 2.01E+18 27.14715 2.01E+18 27.20721 2.02E+18 27.26727 2.02E+18 27.32733 2.03E+18 27.38739 2.03E+18 27.44745 2.03E+18 27.50751 2.04E+18 27.56757 2.04E+18 27.62763 2.05E+18 27.68769 2.05E+18 27.74775 2.06E+18 27.80781 2.06E+18 27.86787 2.07E+18 27.92793 2.07E+18 27.98799 2.08E+18 28.04805 2.08E+18 28.10811 2.08E+18 28.16817 2.09E+18 28.22823 2.09E+18 28.28829 2.10E+18 28.34835 2.10E+18 28.40841 2.11E+18 28.46847 2.11E+18 28.52853 2.12E+18 28.58859 2.12E+18 28.64865 2.12E+18 28.70871 2.13E+18 28.76877 2.13E+18 28.82883 2.14E+18 28.88889 2.14E+18 28.94895 2.15E+18 29.00901 2.15E+18 29.06907 2.16E+18 29.12913 2.16E+18 29.18919 2.16E+18 29.24925 2.17E+18 29.30931 2.17E+18 29.36937 2.18E+18 29.42943 2.18E+18 29.48949 2.19E+18 29.54955 2.19E+18 29.60961 2.20E+18 29.66967 2.20E+18 29.72973 2.20E+18 29.78979 2.21E+18 29.84985 2.21E+18 29.90991 2.22E+18 29.96997 2.22E+18 30.03003 2.23E+18 30.09009 2.23E+18 30.15015 2.24E+18 30.21021 2.24E+18 30.27027 2.24E+18 30.33033 2.25E+18 30.39039 2.25E+18 30.45045 2.26E+18 30.51051 2.26E+18 30.57057 2.27E+18 30.63063 2.27E+18 30.69069 2.28E+18 30.75075 2.28E+18 30.81081 2.28E+18 30.87087 2.29E+18 30.93093 2.29E+18 30.99099 2.30E+18 31.05105 2.30E+18 31.11111 2.31E+18 31.17117 2.31E+18 31.23123 2.32E+18 31.29129 2.32E+18 31.35135 2.32E+18 31.41141 2.33E+18 31.47147 2.33E+18 31.53153 2.34E+18 31.59159 2.34E+18 31.65165 2.35E+18 31.71171 2.35E+18 31.77177 2.36E+18 31.83183 2.36E+18 31.89189 2.36E+18 31.95195 2.37E+18 32.01201 2.37E+18 32.07207 2.38E+18 32.13213 2.38E+18 32.19219 2.39E+18 32.25225 2.39E+18 32.31231 2.40E+18 32.37237 2.40E+18 32.43243 2.40E+18 32.49249 2.41E+18 32.55255 2.41E+18 32.61261 2.42E+18 32.67267 2.42E+18 32.73273 2.43E+18 32.79279 2.43E+18 32.85285 2.44E+18 32.91291 2.44E+18 32.97297 2.44E+18 33.03303 2.45E+18 33.09309 2.45E+18 33.15315 2.46E+18 33.21321 2.46E+18 33.27327 2.47E+18 33.33333 2.47E+18 33.39339 2.48E+18 33.45345 2.48E+18 33.51351 2.48E+18 33.57357 2.49E+18 33.63363 2.49E+18 33.69369 2.50E+18 33.75375 2.50E+18 33.81381 2.51E+18 33.87387 2.51E+18 33.93393 2.52E+18 33.99399 2.52E+18 34.05405 2.52E+18 34.11411 2.53E+18 34.17417 2.53E+18 34.23423 2.54E+18 34.29429 2.54E+18 34.35435 2.55E+18 34.41441 2.55E+18 34.47447 2.56E+18 34.53453 2.56E+18 34.59459 2.56E+18 34.65465 2.57E+18 34.71471 2.57E+18 34.77477 2.58E+18 34.83483 2.58E+18 34.89489 2.59E+18 34.95495 2.59E+18 35.01502 2.60E+18 35.07508 2.60E+18 35.13514 2.60E+18 35.1952 2.61E+18 35.25526 2.61E+18 35.31532 2.62E+18 35.37538 2.62E+18 35.43544 2.63E+18 35.4955 2.63E+18 35.55556 2.64E+18 35.61562 2.64E+18 35.67568 2.65E+18 35.73574 2.65E+18 35.7958 2.65E+18 35.85586 2.66E+18 35.91592 2.66E+18 35.97598 2.67E+18 36.03604 2.67E+18 36.0961 2.68E+18 36.15616 2.68E+18 36.21622 2.69E+18 36.27628 2.69E+18 36.33634 2.69E+18 36.3964 2.70E+18 36.45646 2.70E+18 36.51652 2.71E+18 36.57658 2.71E+18 36.63664 2.72E+18 36.6967 2.72E+18 36.75676 2.73E+18 36.81682 2.73E+18 36.87688 2.73E+18 36.93694 2.74E+18 36.997 2.74E+18 37.05706 2.75E+18 37.11712 2.75E+18 37.17718 2.76E+18 37.23724 2.76E+18 37.2973 2.77E+18 37.35736 2.77E+18 37.41742 2.77E+18 37.47748 2.78E+18 37.53754 2.78E+18 37.5976 2.79E+18 37.65766 2.79E+18 37.71772 2.80E+18 37.77778 2.80E+18 37.83784 2.81E+18 37.8979 2.81E+18 37.95796 2.81E+18 38.01802 2.82E+18 38.07808 2.82E+18 38.13814 2.83E+18 38.1982 2.83E+18 38.25826 2.84E+18 38.31832 2.84E+18 38.37838 2.85E+18 38.43844 2.85E+18 38.4985 2.85E+18 38.55856 2.86E+18 38.61862 2.86E+18 38.67868 2.87E+18 38.73874 2.87E+18 38.7988 2.88E+18 38.85886 2.88E+18 38.91892 2.89E+18 38.97898 2.89E+18 39.03904 2.89E+18 39.0991 2.90E+18 39.15916 2.90E+18 39.21922 2.91E+18 39.27928 2.91E+18 39.33934 2.92E+18 39.3994 2.92E+18 39.45946 2.93E+18 39.51952 2.93E+18 39.57958 2.93E+18 39.63964 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