Hydrophobic polymerized ionic liquids for trace metal solid phase extraction: thallium transfer from hydrochloric acid media DOI: 10.1039/C9NJ00689C poly(IL) IL IL_rad Tl Time, min D +/- Time, min_line D_line D +/- Time, min D +/- 0 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 1 53.42414 1.10605 5 5.50985 0.27549 0.06006 0.61525 51.26630 2.56331 3 50.82366 1.13063 15 8.59374 0.42969 0.12012 0.95120 51.38252 2.56913 5 51.41220 0.53774 30 11.08959 0.55448 0.18018 1.19964 51.35535 2.56777 8 46.88224 1.01192 60 11.71566 0.58578 0.24024 1.40191 51.34991 2.56750 10 49.87462 1.17157 0.30030 1.57487 20 47.58526 1.11095 0.36036 1.72728 0.42042 1.86432 0.48048 1.98937 0.54054 2.10476 0.60060 2.21215 0.66066 2.31280 0.72072 2.40769 0.78078 2.49756 0.84084 2.58304 0.90090 2.66463 0.96096 2.74273 1.02102 2.81770 1.08108 2.88984 1.14114 2.95940 1.20120 3.02660 1.26126 3.09163 1.32132 3.15465 1.38138 3.21582 1.44144 3.27526 1.50150 3.33309 1.56156 3.38942 1.62162 3.44434 1.68168 3.49793 1.74174 3.55028 1.80180 3.60145 1.86186 3.65151 1.92192 3.70051 1.98198 3.74851 2.04204 3.79556 2.10210 3.84170 2.16216 3.88698 2.22222 3.93144 2.28228 3.97511 2.34234 4.01802 2.40240 4.06021 2.46246 4.10172 2.52252 4.14255 2.58258 4.18275 2.64264 4.22234 2.70270 4.26133 2.76276 4.29975 2.82282 4.33763 2.88288 4.37497 2.94294 4.41181 3.00300 4.44814 3.06306 4.48400 3.12312 4.51940 3.18318 4.55435 3.24324 4.58886 3.30330 4.62296 3.36336 4.65664 3.42342 4.68993 3.48348 4.72283 3.54354 4.75536 3.60360 4.78753 3.66366 4.81934 3.72372 4.85081 3.78378 4.88194 3.84384 4.91275 3.90390 4.94324 3.96396 4.97342 4.02402 5.00329 4.08408 5.03288 4.14414 5.06217 4.20420 5.09119 4.26426 5.11993 4.32432 5.14840 4.38438 5.17662 4.44444 5.20457 4.50450 5.23228 4.56456 5.25974 4.62462 5.28697 4.68468 5.31396 4.74474 5.34072 4.80480 5.36726 4.86486 5.39358 4.92492 5.41968 4.98498 5.44557 5.04505 5.47126 5.10511 5.49675 5.16517 5.52203 5.22523 5.54712 5.28529 5.57202 5.34535 5.59674 5.40541 5.62127 5.46547 5.64562 5.52553 5.66979 5.58559 5.69379 5.64565 5.71761 5.70571 5.74127 5.76577 5.76477 5.82583 5.78810 5.88589 5.81127 5.94595 5.83429 6.00601 5.85715 6.06607 5.87986 6.12613 5.90242 6.18619 5.92484 6.24625 5.94711 6.30631 5.96924 6.36637 5.99123 6.42643 6.01308 6.48649 6.03480 6.54655 6.05638 6.60661 6.07783 6.66667 6.09916 6.72673 6.12035 6.78679 6.14142 6.84685 6.16237 6.90691 6.18320 6.96697 6.20390 7.02703 6.22449 7.08709 6.24496 7.14715 6.26531 7.20721 6.28555 7.26727 6.30568 7.32733 6.32570 7.38739 6.34561 7.44745 6.36542 7.50751 6.38511 7.56757 6.40471 7.62763 6.42420 7.68769 6.44358 7.74775 6.46287 7.80781 6.48206 7.86787 6.50115 7.92793 6.52014 7.98799 6.53904 8.04805 6.55785 8.10811 6.57656 8.16817 6.59517 8.22823 6.61370 8.28829 6.63214 8.34835 6.65049 8.40841 6.66875 8.46847 6.68693 8.52853 6.70502 8.58859 6.72302 8.64865 6.74094 8.70871 6.75878 8.76877 6.77654 8.82883 6.79422 8.88889 6.81181 8.94895 6.82933 9.00901 6.84677 9.06907 6.86413 9.12913 6.88142 9.18919 6.89863 9.24925 6.91577 9.30931 6.93283 9.36937 6.94982 9.42943 6.96674 9.48949 6.98358 9.54955 7.00036 9.60961 7.01706 9.66967 7.03370 9.72973 7.05026 9.78979 7.06676 9.84985 7.08319 9.90991 7.09956 9.96997 7.11586 10.03003 7.13209 10.09009 7.14826 10.15015 7.16437 10.21021 7.18041 10.27027 7.19639 10.33033 7.21231 10.39039 7.22816 10.45045 7.24396 10.51051 7.25969 10.57057 7.27537 10.63063 7.29098 10.69069 7.30654 10.75075 7.32204 10.81081 7.33748 10.87087 7.35287 10.93093 7.36819 10.99099 7.38347 11.05105 7.39868 11.11111 7.41384 11.17117 7.42895 11.23123 7.44401 11.29129 7.45901 11.35135 7.47395 11.41141 7.48885 11.47147 7.50369 11.53153 7.51848 11.59159 7.53322 11.65165 7.54791 11.71171 7.56255 11.77177 7.57714 11.83183 7.59168 11.89189 7.60617 11.95195 7.62061 12.01201 7.63500 12.07207 7.64935 12.13213 7.66364 12.19219 7.67789 12.25225 7.69210 12.31231 7.70626 12.37237 7.72037 12.43243 7.73444 12.49249 7.74846 12.55255 7.76243 12.61261 7.77637 12.67267 7.79025 12.73273 7.80410 12.79279 7.81790 12.85285 7.83166 12.91291 7.84537 12.97297 7.85905 13.03303 7.87268 13.09309 7.88627 13.15315 7.89981 13.21321 7.91332 13.27327 7.92679 13.33333 7.94021 13.39339 7.95360 13.45345 7.96694 13.51351 7.98025 13.57357 7.99351 13.63363 8.00674 13.69369 8.01993 13.75375 8.03308 13.81381 8.04619 13.87387 8.05926 13.93393 8.07230 13.99399 8.08530 14.05405 8.09826 14.11411 8.11118 14.17417 8.12407 14.23423 8.13692 14.29429 8.14974 14.35435 8.16252 14.41441 8.17527 14.47447 8.18797 14.53453 8.20065 14.59459 8.21329 14.65465 8.22589 14.71471 8.23846 14.77477 8.25100 14.83483 8.26350 14.89489 8.27597 14.95495 8.28841 15.01502 8.30081 15.07508 8.31318 15.13514 8.32551 15.19520 8.33782 15.25526 8.35009 15.31532 8.36233 15.37538 8.37454 15.43544 8.38671 15.49550 8.39886 15.55556 8.41097 15.61562 8.42305 15.67568 8.43510 15.73574 8.44712 15.79580 8.45911 15.85586 8.47107 15.91592 8.48300 15.97598 8.49490 16.03604 8.50677 16.09610 8.51861 16.15616 8.53042 16.21622 8.54220 16.27628 8.55396 16.33634 8.56568 16.39640 8.57737 16.45646 8.58904 16.51652 8.60068 16.57658 8.61229 16.63664 8.62387 16.69670 8.63542 16.75676 8.64695 16.81682 8.65845 16.87688 8.66992 16.93694 8.68137 16.99700 8.69278 17.05706 8.70417 17.11712 8.71554 17.17718 8.72688 17.23724 8.73819 17.29730 8.74947 17.35736 8.76073 17.41742 8.77196 17.47748 8.78317 17.53754 8.79435 17.59760 8.80551 17.65766 8.81664 17.71772 8.82775 17.77778 8.83883 17.83784 8.84988 17.89790 8.86091 17.95796 8.87192 18.01802 8.88290 18.07808 8.89386 18.13814 8.90479 18.19820 8.91570 18.25826 8.92659 18.31832 8.93745 18.37838 8.94829 18.43844 8.95910 18.49850 8.96989 18.55856 8.98066 18.61862 8.99140 18.67868 9.00212 18.73874 9.01282 18.79880 9.02350 18.85886 9.03415 18.91892 9.04478 18.97898 9.05539 19.03904 9.06597 19.09910 9.07654 19.15916 9.08708 19.21922 9.09760 19.27928 9.10809 19.33934 9.11857 19.39940 9.12902 19.45946 9.13946 19.51952 9.14987 19.57958 9.16026 19.63964 9.17062 19.69970 9.18097 19.75976 9.19130 19.81982 9.20160 19.87988 9.21189 19.93994 9.22215 20.00000 9.23239 20.06006 9.24262 20.12012 9.25282 20.18018 9.26300 20.24024 9.27316 20.30030 9.28331 20.36036 9.29343 20.42042 9.30353 20.48048 9.31361 20.54054 9.32368 20.60060 9.33372 20.66066 9.34374 20.72072 9.35375 20.78078 9.36373 20.84084 9.37370 20.90090 9.38364 20.96096 9.39357 21.02102 9.40348 21.08108 9.41337 21.14114 9.42324 21.20120 9.43309 21.26126 9.44293 21.32132 9.45274 21.38138 9.46254 21.44144 9.47232 21.50150 9.48208 21.56156 9.49182 21.62162 9.50155 21.68168 9.51125 21.74174 9.52094 21.80180 9.53061 21.86186 9.54026 21.92192 9.54990 21.98198 9.55952 22.04204 9.56912 22.10210 9.57870 22.16216 9.58826 22.22222 9.59781 22.28228 9.60734 22.34234 9.61686 22.40240 9.62635 22.46246 9.63583 22.52252 9.64530 22.58258 9.65474 22.64264 9.66417 22.70270 9.67359 22.76276 9.68298 22.82282 9.69236 22.88288 9.70173 22.94294 9.71107 23.00300 9.72040 23.06306 9.72972 23.12312 9.73902 23.18318 9.74830 23.24324 9.75757 23.30330 9.76682 23.36336 9.77605 23.42342 9.78527 23.48348 9.79447 23.54354 9.80366 23.60360 9.81283 23.66366 9.82199 23.72372 9.83113 23.78378 9.84025 23.84384 9.84936 23.90390 9.85846 23.96396 9.86754 24.02402 9.87660 24.08408 9.88565 24.14414 9.89469 24.20420 9.90370 24.26426 9.91271 24.32432 9.92170 24.38438 9.93067 24.44444 9.93963 24.50450 9.94858 24.56456 9.95751 24.62462 9.96643 24.68468 9.97533 24.74474 9.98421 24.80480 9.99309 24.86486 10.00195 24.92492 10.01079 24.98498 10.01962 25.04505 10.02844 25.10511 10.03724 25.16517 10.04603 25.22523 10.05480 25.28529 10.06356 25.34535 10.07231 25.40541 10.08104 25.46547 10.08976 25.52553 10.09846 25.58559 10.10716 25.64565 10.11583 25.70571 10.12450 25.76577 10.13315 25.82583 10.14179 25.88589 10.15041 25.94595 10.15902 26.00601 10.16762 26.06607 10.17620 26.12613 10.18478 26.18619 10.19333 26.24625 10.20188 26.30631 10.21041 26.36637 10.21893 26.42643 10.22744 26.48649 10.23593 26.54655 10.24441 26.60661 10.25288 26.66667 10.26133 26.72673 10.26977 26.78679 10.27820 26.84685 10.28662 26.90691 10.29502 26.96697 10.30342 27.02703 10.31180 27.08709 10.32016 27.14715 10.32852 27.20721 10.33686 27.26727 10.34519 27.32733 10.35351 27.38739 10.36181 27.44745 10.37011 27.50751 10.37839 27.56757 10.38666 27.62763 10.39492 27.68769 10.40316 27.74775 10.41140 27.80781 10.41962 27.86787 10.42783 27.92793 10.43603 27.98799 10.44421 28.04805 10.45239 28.10811 10.46055 28.16817 10.46870 28.22823 10.47684 28.28829 10.48497 28.34835 10.49309 28.40841 10.50119 28.46847 10.50929 28.52853 10.51737 28.58859 10.52544 28.64865 10.53350 28.70871 10.54155 28.76877 10.54959 28.82883 10.55761 28.88889 10.56563 28.94895 10.57363 29.00901 10.58163 29.06907 10.58961 29.12913 10.59758 29.18919 10.60554 29.24925 10.61349 29.30931 10.62143 29.36937 10.62936 29.42943 10.63727 29.48949 10.64518 29.54955 10.65308 29.60961 10.66096 29.66967 10.66883 29.72973 10.67670 29.78979 10.68455 29.84985 10.69239 29.90991 10.70022 29.96997 10.70805 30.03003 10.71586 30.09009 10.72366 30.15015 10.73145 30.21021 10.73923 30.27027 10.74700 30.33033 10.75476 30.39039 10.76251 30.45045 10.77024 30.51051 10.77797 30.57057 10.78569 30.63063 10.79340 30.69069 10.80110 30.75075 10.80879 30.81081 10.81646 30.87087 10.82413 30.93093 10.83179 30.99099 10.83944 31.05105 10.84708 31.11111 10.85471 31.17117 10.86233 31.23123 10.86994 31.29129 10.87754 31.35135 10.88513 31.41141 10.89271 31.47147 10.90028 31.53153 10.90784 31.59159 10.91539 31.65165 10.92293 31.71171 10.93046 31.77177 10.93798 31.83183 10.94550 31.89189 10.95300 31.95195 10.96050 32.01201 10.96798 32.07207 10.97546 32.13213 10.98292 32.19219 10.99038 32.25225 10.99783 32.31231 11.00527 32.37237 11.01270 32.43243 11.02012 32.49249 11.02753 32.55255 11.03493 32.61261 11.04232 32.67267 11.04970 32.73273 11.05708 32.79279 11.06445 32.85285 11.07180 32.91291 11.07915 32.97297 11.08649 33.03303 11.09382 33.09309 11.10114 33.15315 11.10845 33.21321 11.11575 33.27327 11.12305 33.33333 11.13033 33.39339 11.13761 33.45345 11.14488 33.51351 11.15214 33.57357 11.15939 33.63363 11.16663 33.69369 11.17387 33.75375 11.18109 33.81381 11.18831 33.87387 11.19552 33.93393 11.20272 33.99399 11.20991 34.05405 11.21709 34.11411 11.22426 34.17417 11.23143 34.23423 11.23859 34.29429 11.24574 34.35435 11.25288 34.41441 11.26001 34.47447 11.26713 34.53453 11.27425 34.59459 11.28136 34.65465 11.28846 34.71471 11.29555 34.77477 11.30263 34.83483 11.30970 34.89489 11.31677 34.95495 11.32383 35.01502 11.33088 35.07508 11.33792 35.13514 11.34496 35.19520 11.35198 35.25526 11.35900 35.31532 11.36601 35.37538 11.37302 35.43544 11.38001 35.49550 11.38700 35.55556 11.39398 35.61562 11.40095 35.67568 11.40791 35.73574 11.41486 35.79580 11.42181 35.85586 11.42875 35.91592 11.43568 35.97598 11.44261 36.03604 11.44953 36.09610 11.45643 36.15616 11.46334 36.21622 11.47023 36.27628 11.47712 36.33634 11.48399 36.39640 11.49086 36.45646 11.49773 36.51652 11.50458 36.57658 11.51143 36.63664 11.51827 36.69670 11.52511 36.75676 11.53193 36.81682 11.53875 36.87688 11.54556 36.93694 11.55237 36.99700 11.55916 37.05706 11.56595 37.11712 11.57273 37.17718 11.57951 37.23724 11.58627 37.29730 11.59303 37.35736 11.59979 37.41742 11.60653 37.47748 11.61327 37.53754 11.62000 37.59760 11.62672 37.65766 11.63344 37.71772 11.64015 37.77778 11.64685 37.83784 11.65355 37.89790 11.66024 37.95796 11.66692 38.01802 11.67359 38.07808 11.68026 38.13814 11.68692 38.19820 11.69357 38.25826 11.70022 38.31832 11.70686 38.37838 11.71349 38.43844 11.72011 38.49850 11.72673 38.55856 11.73334 38.61862 11.73995 38.67868 11.74655 38.73874 11.75314 38.79880 11.75972 38.85886 11.76630 38.91892 11.77287 38.97898 11.77943 39.03904 11.78599 39.09910 11.79254 39.15916 11.79909 39.21922 11.80562 39.27928 11.81215 39.33934 11.81868 39.39940 11.82519 39.45946 11.83170 39.51952 11.83821 39.57958 11.84471 39.63964 11.85120 39.69970 11.85768 39.75976 11.86416 39.81982 11.87063 39.87988 11.87709 39.93994 11.88355 40.00000 11.89000 40.06006 11.89645 40.12012 11.90289 40.18018 11.90932 40.24024 11.91575 40.30030 11.92216 40.36036 11.92858 40.42042 11.93499 40.48048 11.94139 40.54054 11.94778 40.60060 11.95417 40.66066 11.96055 40.72072 11.96692 40.78078 11.97329 40.84084 11.97966 40.90090 11.98601 40.96096 11.99236 41.02102 11.99871 41.08108 12.00505 41.14114 12.01138 41.20120 12.01770 41.26126 12.02402 41.32132 12.03034 41.38138 12.03664 41.44144 12.04294 41.50150 12.04924 41.56156 12.05553 41.62162 12.06181 41.68168 12.06809 41.74174 12.07436 41.80180 12.08062 41.86186 12.08688 41.92192 12.09314 41.98198 12.09938 42.04204 12.10562 42.10210 12.11186 42.16216 12.11809 42.22222 12.12431 42.28228 12.13053 42.34234 12.13674 42.40240 12.14294 42.46246 12.14914 42.52252 12.15534 42.58258 12.16153 42.64264 12.16771 42.70270 12.17388 42.76276 12.18006 42.82282 12.18622 42.88288 12.19238 42.94294 12.19853 43.00300 12.20468 43.06306 12.21082 43.12312 12.21696 43.18318 12.22309 43.24324 12.22921 43.30330 12.23533 43.36336 12.24145 43.42342 12.24755 43.48348 12.25366 43.54354 12.25975 43.60360 12.26584 43.66366 12.27193 43.72372 12.27801 43.78378 12.28408 43.84384 12.29015 43.90390 12.29622 43.96396 12.30227 44.02402 12.30833 44.08408 12.31437 44.14414 12.32041 44.20420 12.32645 44.26426 12.33248 44.32432 12.33850 44.38438 12.34452 44.44444 12.35054 44.50450 12.35655 44.56456 12.36255 44.62462 12.36855 44.68468 12.37454 44.74474 12.38053 44.80480 12.38651 44.86486 12.39248 44.92492 12.39846 44.98498 12.40442 45.04505 12.41038 45.10511 12.41634 45.16517 12.42229 45.22523 12.42823 45.28529 12.43417 45.34535 12.44010 45.40541 12.44603 45.46547 12.45196 45.52553 12.45787 45.58559 12.46379 45.64565 12.46970 45.70571 12.47560 45.76577 12.48150 45.82583 12.48739 45.88589 12.49328 45.94595 12.49916 46.00601 12.50503 46.06607 12.51091 46.12613 12.51677 46.18619 12.52264 46.24625 12.52849 46.30631 12.53434 46.36637 12.54019 46.42643 12.54603 46.48649 12.55187 46.54655 12.55770 46.60661 12.56353 46.66667 12.56935 46.72673 12.57516 46.78679 12.58098 46.84685 12.58678 46.90691 12.59258 46.96697 12.59838 47.02703 12.60417 47.08709 12.60996 47.14715 12.61574 47.20721 12.62152 47.26727 12.62729 47.32733 12.63306 47.38739 12.63882 47.44745 12.64458 47.50751 12.65033 47.56757 12.65608 47.62763 12.66182 47.68769 12.66756 47.74775 12.67329 47.80781 12.67902 47.86787 12.68474 47.92793 12.69046 47.98799 12.69617 48.04805 12.70188 48.10811 12.70759 48.16817 12.71329 48.22823 12.71898 48.28829 12.72467 48.34835 12.73036 48.40841 12.73604 48.46847 12.74172 48.52853 12.74739 48.58859 12.75305 48.64865 12.75872 48.70871 12.76437 48.76877 12.77003 48.82883 12.77568 48.88889 12.78132 48.94895 12.78696 49.00901 12.79259 49.06907 12.79822 49.12913 12.80385 49.18919 12.80947 49.24925 12.81508 49.30931 12.82070 49.36937 12.82630 49.42943 12.83190 49.48949 12.83750 49.54955 12.84310 49.60961 12.84868 49.66967 12.85427 49.72973 12.85985 49.78979 12.86542 49.84985 12.87100 49.90991 12.87656 49.96997 12.88212 50.03003 12.88768 50.09009 12.89323 50.15015 12.89878 50.21021 12.90433 50.27027 12.90987 50.33033 12.91540 50.39039 12.92093 50.45045 12.92646 50.51051 12.93198 50.57057 12.93750 50.63063 12.94301 50.69069 12.94852 50.75075 12.95403 50.81081 12.95953 50.87087 12.96502 50.93093 12.97051 50.99099 12.97600 51.05105 12.98148 51.11111 12.98696 51.17117 12.99244 51.23123 12.99791 51.29129 13.00337 51.35135 13.00884 51.41141 13.01429 51.47147 13.01975 51.53153 13.02520 51.59159 13.03064 51.65165 13.03608 51.71171 13.04152 51.77177 13.04695 51.83183 13.05238 51.89189 13.05780 51.95195 13.06322 52.01201 13.06864 52.07207 13.07405 52.13213 13.07945 52.19219 13.08486 52.25225 13.09025 52.31231 13.09565 52.37237 13.10104 52.43243 13.10643 52.49249 13.11181 52.55255 13.11719 52.61261 13.12256 52.67267 13.12793 52.73273 13.13330 52.79279 13.13866 52.85285 13.14402 52.91291 13.14937 52.97297 13.15472 53.03303 13.16006 53.09309 13.16541 53.15315 13.17074 53.21321 13.17608 53.27327 13.18141 53.33333 13.18673 53.39339 13.19205 53.45345 13.19737 53.51351 13.20268 53.57357 13.20799 53.63363 13.21330 53.69369 13.21860 53.75375 13.22390 53.81381 13.22919 53.87387 13.23448 53.93393 13.23977 53.99399 13.24505 54.05405 13.25033 54.11411 13.25560 54.17417 13.26087 54.23423 13.26614 54.29429 13.27140 54.35435 13.27666 54.41441 13.28191 54.47447 13.28717 54.53453 13.29241 54.59459 13.29766 54.65465 13.30290 54.71471 13.30813 54.77477 13.31336 54.83483 13.31859 54.89489 13.32381 54.95495 13.32903 55.01502 13.33425 55.07508 13.33946 55.13514 13.34467 55.19520 13.34988 55.25526 13.35508 55.31532 13.36028 55.37538 13.36547 55.43544 13.37066 55.49550 13.37585 55.55556 13.38103 55.61562 13.38621 55.67568 13.39138 55.73574 13.39655 55.79580 13.40172 55.85586 13.40688 55.91592 13.41204 55.97598 13.41720 56.03604 13.42235 56.09610 13.42750 56.15616 13.43265 56.21622 13.43779 56.27628 13.44293 56.33634 13.44806 56.39640 13.45319 56.45646 13.45832 56.51652 13.46344 56.57658 13.46856 56.63664 13.47368 56.69670 13.47879 56.75676 13.48390 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